Hydrogen Borrowing Catalysis with Secondary Alcohols: A New Route for the Generation of β-Branched Carbonyl Compounds.
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DOI: 10.1021/jacs.6b12840
Abstract: A hydrogen borrowing reaction employing secondary alcohols and Ph* (Me5C6) ketones to give β-branched carbonyl products is described (21 examples). This new C-C bond forming process requires low loadings of [Cp*IrCl2]2, relatively low temperatures, and… read more here.
Keywords: borrowing catalysis; hydrogen borrowing; alcohols new; catalysis secondary ... See more keywords