Ni-Catalyzed chemoselective alcoholysis of N-acyloxazolidinones
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DOI: 10.1039/c7gc03534a
Abstract: Although N-acyloxazolidinone-based (catalytic) asymmetric synthetic methodologies occupy an important position in modern organic synthesis, the catalytic cleavage of a chiral auxiliary remains underdeveloped. We report the Ni(cod)2/bipyr.-catalyzed alcoholysis of N-acyloxazolidinones to deliver esters. The reaction… read more here.
Keywords: alcoholysis; chemoselective alcoholysis; catalyzed chemoselective; chemistry ... See more keywords