Mechanistic Insights into La-Catalyzed Amidation of Aldehyde with Amine.
Sign Up to like & getrecommendations! Published in 2019 at "Organic letters"
DOI: 10.1021/acs.orglett.9b04445
Abstract: A new mechanism of La-catalyzed amidation of N-methylbenzylamine with p-chlorobenzaldehyde has been computationally proposed, where L2La[NR1R2] (I) rather than previously proposed L2La[OCHRNR1R2] (II) is the catalytically active species. Interestingly, the side-product alcohol acting as a… read more here.
Keywords: amidation aldehyde; catalyzed amidation; insights catalyzed; aldehyde amine ... See more keywords
Thioaminal Covalent Adaptable Networks via Thiol-Aldehyde-Amine Multicomponent Polymerization.
Sign Up to like & getrecommendations! Published in 2023 at "ACS macro letters"
DOI: 10.1021/acsmacrolett.3c00165
Abstract: Multicomponent polymerization (MCP) has the advantages of high efficiency, mild reaction conditions, and high yield and has been widely used to synthesize multifunctional polymers. In this report, we develop novel covalent adaptable networks (CANs) with… read more here.
Keywords: thiol aldehyde; multicomponent polymerization; adaptable networks; covalent adaptable ... See more keywords
A Versatile Catalyst-Free Perfluoroaryl Azide-Aldehyde-Amine Conjugation Reaction.
Sign Up to like & getrecommendations! Published in 2019 at "Materials chemistry frontiers"
DOI: 10.1039/c8qm00516h
Abstract: A tri-component reaction, involving an electrophilically-activated perfluoroaryl azide, an enolizable aldehyde and an amine, reacts readily at room temperature without any catalysts in solvents including aqueous conditions to yield a stable amidine conjugate. The versatility… read more here.
Keywords: aldehyde amine; conjugation; versatile catalyst; reaction ... See more keywords