Keto-Enol Tautomerization Triggers an Electrophilic Aldehyde Deformylation Reaction by a Nonheme Manganese(III)-Peroxo Complex.
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DOI: 10.1021/jacs.7b10033
Abstract: Oxygen atom transfer by high-valent enzymatic intermediates remains an enigma in chemical catalysis. In particular, manganese is an important first-row metal involved in key biochemical processes, including the biosynthesis of molecular oxygen (through the photosystem… read more here.
Keywords: manganese iii; mechanism; aldehyde deformylation; reaction ... See more keywords