O‐Doped Carbon Nitride: A Recyclable, Metal‐free Photocatalyst for Oxidative Amidation of Aromatic Aldehydes and Amines under Visible Light Irradiation
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DOI: 10.1002/ejoc.202401348
Abstract: Oxidative amidation of aldehydes with amines is a promising strategy for the synthesis of valuable amides. However, conventional methods often use toxic oxidants and additives, resulting in the generation of chemical waste. In this study,… read more here.
Keywords: metal free; visible light; aldehydes amines; oxidative amidation ... See more keywords
Silver-Catalyzed Three-Component Route to Trifluoromethylated 1,2,3-Triazolines Using Aldehydes, Amines, and Trifluorodiazoethane.
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DOI: 10.1021/acs.orglett.9b01159
Abstract: A novel silver-catalyzed domino three-component synthetic route to trifluoromethyl-substituted 1,2,3-triazolines has been realized by employing 2,2,2-trifluorodiazoethane as a 1,3-dipole for the cycloaddition reaction with the Schiff base formed from aldehydes and amines. This step and… read more here.
Keywords: silver catalyzed; component route; catalyzed three; three component ... See more keywords
Copper and N-heterocyclic carbene (NHC) catalyzed oxidative amidation of aldehydes with amines
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DOI: 10.1055/a-1343-5203
Abstract: A one-pot two-step oxidative process using tert-butyl hydroperoxide (TBHP) mediated transformation of aldehydes and amines into amides catalyzed by Copper (I) - Iodide and N-heterocyclic carbenes is developed. The process utilized is additive-free, which does… read more here.
Keywords: carbene nhc; nhc catalyzed; copper; copper heterocyclic ... See more keywords