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Published in 2021 at "Organic letters"
DOI: 10.1021/acs.orglett.1c01128
Abstract: Herein, we report a novel organocatalytic process for synthesis of complex 1,3,4-oxadiazoles from readily accessible aldehydes. By exploiting the nucleophilicity of the putative Breslow intermediate and the inherent electrophilicity of α-diazo iodonium triflate, we have…
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Keywords:
aldehydes diazo;
diazo iodonium;
cyclization;
iodonium triflate ... See more keywords