Stepwise degradation of hydroxyl compounds to aldehydes via successive C-C bond cleavage.
Sign Up to like & getrecommendations! Published in 2019 at "Chemical communications"
DOI: 10.1039/c8cc09504c
Abstract: Stepwise degradation of hydroxyl compounds to aldehydes via successive cleavage of C-C bonds was achieved by using a bimetallic catalytic system (PdCl2 + CuCl) without any ligands and additives. The broad applicability is expanded to… read more here.
Keywords: aldehydes via; compounds aldehydes; via successive; stepwise degradation ... See more keywords
Synthesis of Diversified Pyrazolo[3,4-b]pyridine Frameworks from 5-Aminopyrazoles and Alkynyl Aldehydes via Switchable C≡C Bond Activation Approaches
Sign Up to like & getrecommendations! Published in 2022 at "Molecules"
DOI: 10.3390/molecules27196381
Abstract: A cascade 6-endo-dig cyclization reaction was developed for the switchable synthesis of halogen and non-halogen-functionalized pyrazolo[3,4-b]pyridines from 5-aminopyrazoles and alkynyl aldehydes via C≡C bond activation with silver, iodine, or NBS. In addition to its wide… read more here.
Keywords: aminopyrazoles alkynyl; aldehydes via; alkynyl aldehydes; bond activation ... See more keywords