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Published in 2020 at "Structural Chemistry"
DOI: 10.1007/s11224-020-01538-4
Abstract: The origin of the experimentally known preference for [6,6] bonds in cycloaddition reactions involving C60 has been computationally explored. To this end, we examined the reactions of 1,3-dienes with fullerene (C60) in the context of…
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Keywords:
diels alder;
reactivity enhancement;
enhancement diels;
reactivity ... See more keywords
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Published in 2019 at "Tetrahedron Letters"
DOI: 10.1016/j.tetlet.2019.04.027
Abstract: Abstract The synthesis of novel of 4,5,6,7-tetrahydrobenzoxazol-2-ones is herein reported. They were obtained in moderate to good yields by a highly regio- and stereoselective Diels-Alder cycloaddition of N-substituted exo-oxazolidin-2-one dienes with chalcones or bis-chalcones as…
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Keywords:
oxazolidin one;
one dienes;
alder cycloaddition;
exo oxazolidin ... See more keywords
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Published in 2019 at "Organic letters"
DOI: 10.1021/acs.orglett.9b02457
Abstract: An expedient route to access the functionalized structural core of aflavinines has been developed starting from three readily available fragments over 12 steps in 29.1% overall yield without using any transition metal catalysis. The key…
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Keywords:
tandem intramolecular;
diels alder;
core aflavinines;
structural core ... See more keywords
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Published in 2022 at "ACS macro letters"
DOI: 10.1021/acsmacrolett.2c00616
Abstract: Surface-aligned liquid-crystal networks (LCNs) offer a solution for developing functional materials capable of performing a range of tasks, including actuation, shape memory, and surfaces patterning. Here we show that Diels-Alder cycloaddition can be used to…
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Keywords:
liquid crystal;
diels alder;
alder cycloaddition;
surface aligned ... See more keywords
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Published in 2017 at "Organic chemistry frontiers"
DOI: 10.1039/c7qo00290d
Abstract: We introduce Li+ involving cycloadditions between acetylene and ring-like cycloparaphenylenes (CPPs) in theory. Orbital analysis suggests an inverse electron-demand mechanism in which the diene CPP acts as an electron acceptor. Partial electron transfer to Li+…
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Keywords:
diels alder;
cationic prompted;
study cationic;
mechanistic study ... See more keywords
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Published in 2018 at "Catalysts"
DOI: 10.3390/catal8060253
Abstract: The selective production of p-xylene and other aromatics starting from sugars and bioderived ethylene offers great promise and can eliminate the need for separation of xylene isomers, as well as decreasing dependency on fossil resources…
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Keywords:
diels alder;
production;
xylene;
alder cycloaddition ... See more keywords
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2
Published in 2020 at "Molecules"
DOI: 10.3390/molecules25225373
Abstract: PAHs (polycyclic aromatics hydrocarbons), the compound group that contains perylene and its derivatives, including functionalized ones, have attracted a great deal of interest in many fields of science and modern technology. This review presents all…
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Keywords:
cycloaddition;
diels alder;
perylene derivatives;
strategy ... See more keywords