Eugenol-based thermally stable thermosets by Alder-ene reaction: From synthesis to thermal degradation
Sign Up to like & getrecommendations! Published in 2019 at "European Polymer Journal"
DOI: 10.1016/j.eurpolymj.2019.05.018
Abstract: Performing thermostable materials such as phenolic or epoxy networks are classically obtained from petrobased and harmful monomers. In this study, alternative solutions based on renewable eugenol trifunctional monomer (TEP) are proposed. Thus, innovative biobased Alder-ene… read more here.
Keywords: eugenol based; stable thermosets; degradation; alder ene ... See more keywords
An enzymatic Alder-ene reaction
Sign Up to like & getrecommendations! Published in 2020 at "Nature"
DOI: 10.1038/s41586-020-2743-5
Abstract: An ongoing challenge in chemical research is to design catalysts that select the outcomes of the reactions of complex molecules. Chemists rely on organo- or transition metal catalysts to control stereo-, regio-, and periselectivity (selectivity… read more here.
Keywords: alder ene; enzymatic alder; biology; reaction ... See more keywords
Organocopper triggered cyclization of conjugated dienynes via tandem SN2′/Alder-ene reaction
Sign Up to like & getrecommendations! Published in 2018 at "Organic chemistry frontiers"
DOI: 10.1039/c7qo00288b
Abstract: Propargylic carbonates were converted to indenes through a SN2′/Alder-ene cascade triggered by organocopper reagents. The reaction tolerates different organocopper species generated either from organolithiums or Grignard reagents. A catalytic version of this strategy could be… read more here.
Keywords: alder ene; organocopper triggered; reaction; sn2 alder ... See more keywords