Amine‐Catalyzed Aldol Addition of Dihydroxyacetone for Bio‐Based Flame Retardants
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DOI: 10.1002/cctc.202501139
Abstract: A new catalytic method was developed for synthesizing a sustainable phosphorus‐based flame retardant (PFR) from dihydroxyacetone (DHA), a triose derived from hexoses or glycerol oxidation, e.g., for PUR applications. The study first investigates alkyl amine… read more here.
Keywords: amine catalyzed; based flame; dihydroxyacetone; aldol addition ... See more keywords
l-proline modulated zirconium metal organic frameworks: Simple chiral catalysts for the aldol addition reaction
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Catalysis"
DOI: 10.1016/j.jcat.2018.06.013
Abstract: Abstract Three l -proline modulated zirconium based MOFs denoted as UiO-66, Zr-NDC (NDC = 2,6-Naphthalenedicarboxylate) and UiO-67 were synthesized, characterized and explored as heterogeneous catalyst in diastereoselective aldol addition reactions between 4-nitrobenzaldehyde and linear/cyclic ketones. Upon l… read more here.
Keywords: chiral catalysts; proline modulated; proline; modulated zirconium ... See more keywords