Sulfur Dioxide Complexes of Main-Group Elements: from SO20 to SO2- and SO22- upon Coordination to Aluminum and Silicon Difluorides.
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DOI: 10.1021/acs.inorgchem.9b03780
Abstract: The AlF2(O2S) and SiF2(O2S) complexes with bidentately coordinated sulfur dioxide ligands were prepared via the reactions of aluminum and silicon atoms with SO2F2 under UV-vis irradiation in cryogenic matrixes. The products were identified by infrared… read more here.
Keywords: aluminum silicon; sulfur dioxide; sif2 o2s; alf2 o2s ... See more keywords