Poly(arylisocyanides) as Versatile, Enantiodiscriminating Alignment Media for Small Molecules.
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DOI: 10.1002/cplu.202100507
Abstract: Lyotropic liquid crystalline (LLC) phases of amino acid derived polyarylisocyanides were employed as chiral alignment media for the measurement of residual dipolar couplings (RDCs) of small chiral organic molecules. Anisotropic samples in CDCl3 displayed quadrupolar… read more here.
Keywords: alignment media; versatile enantiodiscriminating; poly arylisocyanides; media small ... See more keywords
Programmable alignment media from self-assembled oligopeptide amphiphiles for the measurement of independent sets of residual dipolar couplings in organic solvents
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DOI: 10.1039/d2sc01057g
Abstract: NMR spectroscopy in anisotropic media has emerged as a powerful technique for the structural elucidation of organic molecules. Its application requires weak alignment of analytes by means of suitable alignment media. Although a number of… read more here.
Keywords: alignment media; organic solvents; residual dipolar; sets residual ... See more keywords