Photofluorination of Aliphatic C-H Bonds Promoted by the Phthalimide Group.
Sign Up to like & getrecommendations! Published in 2018 at "Organic letters"
DOI: 10.1021/acs.orglett.8b00133
Abstract: Aliphatic C-H fluorination of phthalimide derivatives with Selectfluor was investigated under photoirradiation conditions. The reaction did not require any additive or catalyst and afforded C-H fluorinated products in moderate to good yields. It is likely… read more here.
Keywords: aliphatic bonds; bonds promoted; promoted phthalimide; photofluorination aliphatic ... See more keywords
Highly Enantioselective Oxidation of Nonactivated Aliphatic C–H Bonds with Hydrogen Peroxide Catalyzed by Manganese Complexes
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DOI: 10.1021/acscentsci.6b00368
Abstract: Monosubstituted cycloalkanes undergo regio- and enantioselective aliphatic C–H oxidation with H2O2 catalyzed by biologically inspired manganese catalysts. The reaction furnishes the corresponding ketones resulting from oxidation at C3 and C4 methylenic sites (K3 and K4,… read more here.
Keywords: aliphatic bonds; oxidation nonactivated; enantioselective oxidation; oxidation ... See more keywords