Palladium-Catalyzed Enantioselective Cycloadditions of Aliphatic 1,4-Dipoles: Access to Chiral Cyclohexanes and Spiro [2.4] heptanes.
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DOI: 10.1021/jacs.0c08348
Abstract: Design and exploration of new intermediates for chemo-, regio-, and stereoselective cycloadditions remain a formidable challenge in modern organic synthesis. Compared to the well-developed 1,3-dipolar cycloadditions, Pd-catalyzed1,4-dipolar cycloadditions are generally limited to specialized substrates due… read more here.
Keywords: aliphatic dipoles; spiro heptanes; enantioselective cycloadditions; palladium catalyzed ... See more keywords