Transition metal-free regioselective synthesis of triazolyl aliphatic sulfonyl fluorides
Sign Up to like & getrecommendations! Published in 2021 at "Tetrahedron"
DOI: 10.1016/j.tet.2021.132425
Abstract: Abstract An efficient and metal-free method for exclusively regioselective construction of aliphatic sulfonyl fluoride moiety at the C4 position of 1,2,3-triazole ring was successfully developed from the cycloaddition between but-3-ene-1, 3-disulfonyl difluoride (BDF) and organic… read more here.
Keywords: metal free; transition metal; aliphatic sulfonyl; free regioselective ... See more keywords
EnT-Mediated N-S Bond Homolysis of a Bifunctional Reagent Leading to Aliphatic Sulfonyl Fluorides.
Sign Up to like & getrecommendations! Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c11295
Abstract: Sulfur(VI) fluoride exchange (SuFEx) gives rise to a plethora of high-valent sulfur linkages; however, the availability of (aliphatic) sulfonyl fluoride manifolds lag behind, owing to the limited sources of introducing the SO2F moiety via a… read more here.
Keywords: reagent; bond homolysis; aliphatic sulfonyl; sulfonyl fluorides ... See more keywords
A rapid access to aliphatic sulfonyl fluorides
Sign Up to like & getrecommendations! Published in 2019 at "Nature Communications"
DOI: 10.1038/s41467-019-11805-6
Abstract: The past few years have witnessed a fast-growing research interest on the study of sulfonyl fluorides as reactive probes in chemical biology and molecular pharmacology, which raises an urgent need for the development of effective… read more here.
Keywords: aliphatic sulfonyl; sulfonyl fluorides; pharmacology; biology ... See more keywords