Surprising Differences of Alkane C‐H Activation Catalyzed by Ruthenium Nanoparticles: Complex Surface‐Substrate Recognition?
Sign Up to like & getrecommendations! Published in 2018 at "ChemCatChem"
DOI: 10.1002/cctc.201801022
Abstract: The activation of C−H bonds of alkanes remains a major challenge for chemistry. In a series of deuteration experiments with D2 in contact with bis‐(diphenylphosphino) butane (dppb) stabilized ruthenium nanoparticles (liquid substrates, 60 °C, 6 bar D2)… read more here.
Keywords: ruthenium nanoparticles; surprising differences; differences alkane; alkane activation ... See more keywords
Isolated metal atoms and clusters for alkane activation: translating knowledge from enzymatic and homogeneous to heterogeneous systems
Sign Up to like & getrecommendations! Published in 2021 at "Chem"
DOI: 10.1016/j.chempr.2021.04.001
Abstract: Summary Activation of alkanes can be achieved with different types of catalysts, spanning over enzymes, homogeneous and heterogeneous metal catalysts. Though a tremendous amount of knowledge has been accumulated in the literature, the connections between… read more here.
Keywords: activation; homogeneous heterogeneous; knowledge; isolated metal ... See more keywords