Ni-Catalyzed Alkene Carboacylation via Amide C-N Bond Activation.
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DOI: 10.1021/jacs.7b06191
Abstract: We report Ni-catalyzed formal carboacylation of o-allylbenzamides with arylboronic acid pinacol esters. The reaction is triggered by oxidative addition of an activated amide C-N bond to a Ni(0) catalyst and proceeds via alkene insertion into… read more here.
Keywords: alkene carboacylation; carboacylation; bond; bond activation ... See more keywords