C-H Functionalization of Amines via Alkene-Derived Nucleophiles through Cooperative Action of Chiral and Achiral Lewis Acid Catalysts: Applications in Enantioselective Synthesis.
Sign Up to like & getrecommendations! Published in 2018 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.8b06699
Abstract: Catalytic transformations of α-amino C-H bonds to afford valuable enantiomerically enriched α-substituted amines, entities that are prevalent in pharmaceuticals and bioactive natural products, have been developed. Typically, such processes are carried out under oxidative conditions… read more here.
Keywords: derived nucleophiles; alkene derived; functionalization amines; amines via ... See more keywords
Electro-/photocatalytic alkene-derived radical cation chemistry: recent advances in synthetic applications.
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DOI: 10.1039/d2cs00013j
Abstract: Alkene-derived radical cations are versatile reactive intermediates and have been widely applied in the construction of complex functionalized molecules and cyclic systems for chemical synthesis. Therefore, the synthetic application of these alkene-derived radical cations represents… read more here.
Keywords: alkene derived; chemistry; derived radical; recent advances ... See more keywords