Stereoselective Synthesis of Isoxazolidines via Copper-Catalyzed Alkene Diamination.
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DOI: 10.1021/acscatal.7b01362
Abstract: A convenient copper-catalyzed intramolecular/intermolecular alkene diamination reaction to synthesize 3-aminomethyl-functionalized isoxazolidines under mild reaction conditions and with generally high levels of diastereoselectivity was achieved. This reaction demonstrates that previously underutilized unsaturated carbamates are good [Cu]-catalyzed… read more here.
Keywords: diamination; stereoselective synthesis; reaction; alkene diamination ... See more keywords