Alkene Hydrosilylation on Oxide‐Supported Pt‐Ligand Single‐Site Catalysts
Sign Up to like & getrecommendations! Published in 2019 at "ChemCatChem"
DOI: 10.1002/cctc.201900530
Abstract: Heterogeneous single‐site catalysts (SSCs), widely regarded as promising next‐generation catalysts, blend the easy recovery of traditional heterogeneous catalysts with desired features of homogeneous catalysts: high fraction of active sites and uniform metal centers. We previously… read more here.
Keywords: alkene hydrosilylation; ligand; single site; site catalysts ... See more keywords
Control over Selectivity in Alkene Hydrosilylation Catalyzed by Cobalt(III) Hydride Complexes.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c02094
Abstract: Two new bisphosphine [PCP] pincer cobalt(III) hydrides, [(L1)Co(PMe3)(H)(Cl)] (L11, L1 = 2,6-((Ph2P)(Et)N)2C6H3) and [(L2)Co(PMe3)(H)(Cl)] (L21, L2 = 2,6-((iPr2P)(Et)N)2C6H3), as well as one new bissilylene [SiCSi] pincer cobalt(III) hydride, [(L3)Co(PMe3)(H)(Cl)] (L31, L3 = 1,3-((PhC(tBuN)2Si)(Et)N)2C6H3), were synthesized… read more here.
Keywords: iii hydride; cobalt; cobalt iii; alkene hydrosilylation ... See more keywords