Mechanistic insights into rare-earth-catalysed C–H alkylation of sulfides: sulfide facilitating alkene insertion and beyond
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DOI: 10.1039/d2ra02180c
Abstract: The catalytic C–H alkylation with alkenes is of much interest and importance, as it offers a 100% atom efficient route for C–C bond construction. In the past decade, great progress in rare-earth catalysed C–H alkylation… read more here.
Keywords: alkene insertion; alkylation; earth catalysed; insertion ... See more keywords
Accessing Aryldifluoromethyl Derivatives through Alkene Insertion into Benzylic C–F Bonds
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DOI: 10.1055/a-2068-7065
Abstract: Herein, we report a formal insertion of alkenes into a benzylic C-F bond of electron deficient perfluoroalkylarenes under organophotocatalytic conditions using Et3N·3HF as external fluoride source. The absence of fluorides scavenger or other external reductant… read more here.
Keywords: alkene insertion; insertion; accessing aryldifluoromethyl; insertion benzylic ... See more keywords