Hydroamination of Unactivated Alkenes with Aliphatic Azides.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c07643
Abstract: We report here an efficient and highly diastereoselective intermolecular anti-Markovnikov hydroamination of unactivated alkenes with aliphatic azides in the presence of silane. The system tolerates a wide range of azides and alkenes and operates with… read more here.
Keywords: alkenes aliphatic; hydroamination unactivated; unactivated alkenes; aliphatic azides ... See more keywords
Asymmetric intermolecular allylic C–H amination of alkenes with aliphatic amines
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DOI: 10.1126/science.abq1274
Abstract: Aliphatic allylic amines are found in a great variety of complex and biorelevant molecules. The direct allylic C–H amination of alkenes serves as the most straightforward method toward these motifs. However, use of widely available… read more here.
Keywords: alkenes aliphatic; amination alkenes; internal alkenes; allylic amination ... See more keywords