Selective Difunctionalization of Unactivated Aliphatic Alkenes Enabled by a Metal-Metallaaromatic Catalytic System.
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DOI: 10.1021/jacs.1c12586
Abstract: The design of organometallic catalysts is crucial in the development of catalytic reactions. Herein, we describe a heterometallic [Os-Cu] complex with the characteristics of bimetallics, metallaaromatics, and pincer complexes. This complex serves as a highly… read more here.
Keywords: selective difunctionalization; alkenes enabled; metal metallaaromatic; unactivated aliphatic ... See more keywords
Remote and Proximal Hydroaminoalkylation of Alkenes Enabled by Photoredox/Nickel Dual Catalysis.
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DOI: 10.1021/jacs.2c08039
Abstract: A mild and site-selective hydroaminoalkylation of activated and unactivated alkenes via dual photoredox/Ni catalysis is developed. This dual catalytic strategy enables exclusive access to α-selective products, which is complementary to previously reported photocatalytic hydroaminoalkylation of… read more here.
Keywords: alkenes enabled; catalysis; remote proximal; hydroaminoalkylation ... See more keywords