Photoinduced Vicinal Sulfamoyloximation of Alkenes: Harnessing Bifunctional Nitrosamines via a Rapid Radical Trapping Strategy.
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DOI: 10.1021/acs.orglett.4c02245
Abstract: We developed a photoinduced method for vicinal sulfamoyloximation of alkenes using N-nitrosamines as bifunctional reagents, with DABSO serving as both a sulfonyl source and a rapid aminyl radical trap. This strategy prevents radical recombination, enabling… read more here.
Keywords: alkenes harnessing; vicinal sulfamoyloximation; sulfamoyloximation alkenes; strategy ... See more keywords