Mode of Activation of Cobalt(II) Amides for Catalytic Hydrosilylation of Alkenes with Tertiary Silanes.
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DOI: 10.1021/jacs.6b12938
Abstract: Cobalt(II) complexes capable of catalyzing alkene hydrosilylation in the absence of external activators are rarely known, and their activation mode has remained poorly understood. We present here that cobalt(II) amide complexes, [Co(N(SiMe3)2)2] and its NHC… read more here.
Keywords: cobalt; alkenes tertiary; cobalt amides; hydrosilylation alkenes ... See more keywords