Reductive Cross-Coupling of Unreactive Electrophiles.
Sign Up to like & getrecommendations! Published in 2022 at "Accounts of chemical research"
DOI: 10.1021/acs.accounts.2c00381
Abstract: ConspectusTransition-metal-catalyzed reductive coupling of electrophiles has emerged as a powerful tool for the construction of molecules. While major achievements have been made in the field of cross-couplings between organic halides and pseudohalides, an increasing number… read more here.
Keywords: carbon; cross coupling; chemistry; cross ... See more keywords
Regiodivergent Iridium(III)-Catalyzed Diamination of Alkenyl Amides with Secondary Amines: Complementary Access to γ- or δ-Lactams.
Sign Up to like & getrecommendations! Published in 2018 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.7b11455
Abstract: Alkenyl N-pivaloylhydroxamates undergo an Ir(III)-catalyzed diamination of the alkene with simple exogenous secondary amines under extraordinarily mild reaction conditions. The regioselectivity of the diamination is controlled by the solvent and the electronics of the cyclopentadienyl… read more here.
Keywords: diamination; secondary amines; regiodivergent iridium; catalyzed diamination ... See more keywords
Palladium-catalyzed cross-coupling of (hetero)aryl or alkenyl sulfonates with aryl titanium as the multi-functional reagent
Sign Up to like & getrecommendations! Published in 2020 at "Organic chemistry frontiers"
DOI: 10.1039/c9qo01537j
Abstract: The first palladium-catalyzed cross-coupling reaction of aryl/heteroaryl and alkenyl mesylates and tosylates with aryl titanium as the multi-functional reagent is reported. Using the catalyst system of Pd(OAc)2 associated with the new NMe2-CM-Phos (L14), a broad… read more here.
Keywords: aryl titanium; alkenyl; palladium catalyzed; catalyzed cross ... See more keywords
Transition metal-free and regioselective alkenyl C–S cross-coupling reaction of alkenylsulfonium salts
Sign Up to like & getrecommendations! Published in 2023 at "Organic Chemistry Frontiers"
DOI: 10.1039/d3qo00507k
Abstract: A novel and highly efficient strategy for the construction of diverse alkenyl sulfoxides via transition metal-free C–S cross-coupling of sulfenate anions with alkenylsulfonium salts is reported. read more here.
Keywords: cross coupling; metal free; transition metal; alkenyl ... See more keywords