sFrom selective transfer hydrogenation to selective hydrogen auto-transfer process: An efficient method for the synthesis of alkenyl ketones via iridium-catalyzed α-alkylation of ketones with alkenyl alcohols
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Catalysis"
DOI: 10.1016/j.jcat.2021.08.038
Abstract: Abstract A strategy for the synthesis of alkenyl alcohols via the α-alkylation of ketones with alkenyl alcohols has proposed and accomplished. In the presence of a metal-ligand bifunctional catalyst [Cp*Ir(2,2’-bpyO)(H2O)], a series of desirable products… read more here.
Keywords: alkylation ketones; selective transfer; transfer; alkenyl alcohols ... See more keywords
Chain Walking as a Strategy for Iridium-Catalyzed Migratory Amidation of Alkenyl Alcohols to Access α-Amino Ketones.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c00948
Abstract: Catalytic carbon-nitrogen bond formation in hydrocarbons is an appealing synthetic tool to access valuable nitrogen-containing compounds. Although a number of synthetic approaches have been developed to construct a bifunctional α-amino carbonyl scaffold in this realm,… read more here.
Keywords: amidation; chain walking; alkenyl alcohols; amino ... See more keywords