Articles with "alkenyl bond" as a keyword



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Palladium(II)-Catalyzed Stereospecific Alkenyl C–H Bond Alkylation of Allylamines with Alkyl Iodides

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Published in 2019 at "ACS Catalysis"

DOI: 10.1021/acscatal.8b04415

Abstract: A palladium-catalyzed stereospecific alkylation of allylamines with primary and secondary alkyl iodides is described. Isoquinoline-1-carboxamide (IQA) acts as directing group to generate multisubstituted olefin products in cis configuration in moderate to good yields. Mechanistic studies… read more here.

Keywords: alkenyl bond; catalyzed stereospecific; palladium catalyzed; alkylation allylamines ... See more keywords