Site- and Stereoselective Synthesis of Alkenyl Chlorides by Dual Functionalization of Internal Alkynes via Photoredox/Nickel Catalysis.
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DOI: 10.1021/jacs.3c02748
Abstract: Herein, we report a redox-neutral and atom-economical protocol to synthesize valuable alkenyl chlorides from unactivated internal alkynes and abundant organochlorides via photoredox and nickel catalysis. This protocol enables the site- and stereoselective addition of organochlorides… read more here.
Keywords: internal alkynes; nickel catalysis; via photoredox; site stereoselective ... See more keywords