Highly E-Selective, Stereoconvergent Nickel-Catalyzed Suzuki–Miyaura Cross-Coupling of Alkenyl Ethers
Sign Up to like & getrecommendations! Published in 2019 at "Organic Letters"
DOI: 10.1021/acs.orglett.9b00946
Abstract: An improved method for the nickel-catalyzed Suzuki–Miyaura cross-coupling of alkenyl ethers is reported. This stereoconvergent protocol allows for the utilization of a wide range of alkenyl ethers and aryl boronic esters for the synthesis of… read more here.
Keywords: alkenyl ethers; catalyzed suzuki; suzuki miyaura; nickel catalyzed ... See more keywords
Nickel-Catalyzed Remote Asymmetric Hydroalkylation of Alkenyl Ethers to Access Ethers of Chiral Dialkyl Carbinols.
Sign Up to like & getrecommendations! Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.3c02950
Abstract: Site- and enantio-selective alkyl-alkyl bond formation is privileged in the retrosynthetic analysis due to the universality of sp3-hybridized carbon atoms in organic molecules. Herein, we report a nickel-catalyzed remote asymmetric hydroalkylation of alkenyl ethers via… read more here.
Keywords: asymmetric hydroalkylation; nickel catalyzed; remote asymmetric; alkenyl ethers ... See more keywords