Halohydroxylation of alkenyl MIDA boronates: switchable stereoselectivity induced by B(MIDA) substituent.
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DOI: 10.1039/d0cc00722f
Abstract: The synthesis of α-boryl halohydrins via difunctionalization of alkenyl MIDA boronates has been reported. Intriguing stereoselectivity was found with different halogen sources, which arises from the special stabilizing effect of the B(MIDA) moiety. The transformation… read more here.
Keywords: mida; halohydroxylation alkenyl; alkenyl mida; stereoselectivity ... See more keywords
Synthetic Transformations of Alkenyl MIDA Boronates toward the Efficient Construction of Organoborons
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DOI: 10.1055/s-0036-1591958
Abstract: The attachment of N -methyliminodiacetyl boron (MIDA boron) to alkenes leads to a new type of activated alkenes. Synthetic manipulation of the alkene double bond while retaining the boron moiety offers an unprecedented opportunity for… read more here.
Keywords: transformations alkenyl; alkenyl mida; mida boronates; synthetic transformations ... See more keywords