Recent Advances in Alkenyl sp2 C-H and C-F Bond Functionalizations: Scope, Mechanism, and Applications.
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DOI: 10.1021/acs.chemrev.2c00032
Abstract: Alkenes and their derivatives are featured widely in a variety of natural products, pharmaceuticals, and advanced materials. Significant efforts have been made toward the development of new and practical methods to access this important class… read more here.
Keywords: review; bond functionalizations; alkenyl sp2; sp2 bond ... See more keywords
Regiodivergent Synthesis of Eight-Membered Benzosilacycles via Palladium-Catalyzed Alkenyl C(sp2)-H Activation.
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DOI: 10.1021/acs.orglett.5c02531
Abstract: Herein we report a general and efficient method for the regiodivergent synthesis of medium-sized eight-membered aryl- and alkenylsilacycles via a palladium-catalyzed alkenyl C(sp2)-H activation/ring expansion cascade. This protocol features a broad substrate scope regarding o-bromostyrenes… read more here.
Keywords: eight membered; palladium catalyzed; regiodivergent synthesis; alkenyl sp2 ... See more keywords