Palladium/Light Induced Radical Alkenylation and Allylation of Alkyl Iodides Using Alkenyl and Allylic Sulfones.
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DOI: 10.1021/acs.orglett.7b04050
Abstract: Alkenylation and allylation of alkyl iodides with alkenyl and allyl sulfones, respectively, took place under Pd/photoirradiation system. The initial alkyl radical, derived from a single electron transfer between Pd(0) and RI, underwent the title transformations.… read more here.
Keywords: allylation alkyl; alkyl iodides; alkenylation allylation;