Peripheral Substitution of Tetraphenyl Porphyrins: Fine-Tuning Self-Assembly for Enhanced Electroluminescence.
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DOI: 10.1002/cplu.201700416
Abstract: This study reports the synthesis of two novel zinc porphyrin families bearing four or eight alkoxy chains at their peripheral phenyl rings, with the length of the alkoxy chains ranging from 2, to 6, and… read more here.
Keywords: peripheral substitution; fine tuning; tetraphenyl porphyrins; substitution tetraphenyl ... See more keywords
Aliphatic Chains and External Pressure as Tools for Fine-Tuning Spin Transition Temperature and Cooperativity.
Sign Up to like & getrecommendations! Published in 2025 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.5c03403
Abstract: In switchable spin crossover (SCO) molecular materials, control of their critical temperature and cooperativeness is essential for practical applications. This requires systematic fine-tuning of the molecular packing in the crystal. Therefore, here we report on… read more here.
Keywords: pressure; temperature; external pressure; alkoxy chains ... See more keywords
Synthesis, mesomorphic and magnetic properties at room temperature of biphenyl ester-aromatic imine with terminal alkoxy chains and methoxy substituent
Sign Up to like & getrecommendations! Published in 2024 at "Liquid Crystals"
DOI: 10.1080/02678292.2024.2321475
Abstract: ABSTRACT A series of calamitic biphenyl ester-aromatic imine derived from the reaction of 4-formylphenyl-4’-(alkyloxy)-[1,1’-biphenyl]-4-carboxylate and p-anisidine have been successfully synthesised and characterised. The general molecular structures of ultimate compounds show the central fragment made up… read more here.
Keywords: alkoxy chains; ester aromatic; aromatic imine; terminal alkoxy ... See more keywords
Crystal Structures of Bis(diphenylglyoximato)–Nickel(II) Complex with Varying Alkoxy Chain Lengths
Sign Up to like & getrecommendations! Published in 2017 at "Bulletin of the Chemical Society of Japan"
DOI: 10.1246/bcsj.20170036
Abstract: Crystal structures of eight derivatives of bis(diphenylglyoximato)–nickel(II), bearing four alkoxy chains of different lengths, were determined by single-crystal X-ray crystallography. Sequential transition of packing structures by chain elongation was observed. The packing structures were typically… read more here.
Keywords: chain; crystal structures; bis diphenylglyoximato; alkoxy chains ... See more keywords