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Published in 2022 at "Chemical Science"
DOI: 10.1039/d2sc04103k
Abstract: A general rhodium-catalyzed selective carbonylative coupling of unactivated alkyl chlorides with aliphatic alcohols or phenols to the corresponding esters is presented for the first time. Crucial for this transformation is the addition of sodium iodide,…
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Keywords:
unactivated alkyl;
alkyl chlorides;
catalyzed alkoxycarbonylation;
alkoxycarbonylation unactivated ... See more keywords