Catalytic Enantioselective Synthesis of Silicon-Stereogenic Alkoxysilanes and Siloxanes
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DOI: 10.1055/a-1503-7976
Abstract: A Rh-catalyzed enantioselective intermolecular dehydrogenative Si–O coupling of dihydrosilanes with alcohols and silanols is demonstrated. Rh(I) catalyst equipped with a Josiphos ligand enables the highly enantioselective alcoholysis process of dihydrosilanes, giving access to a variety… read more here.
Keywords: alkoxysilanes siloxanes; silicon stereogenic; silicon; stereogenic alkoxysilanes ... See more keywords