Lipase‐catalyzed hydrazine insertion for the synthesis of N′‐alkyl benzohydrazides
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DOI: 10.1002/bab.2335
Abstract: N′‐alkyl benzohydrazides are classic organic compounds that have been widely utilized in organic chemistry. In this study, an efficient method was developed for the synthesis of N′‐alkyl benzohydrazides by hydrazine insertion catalyzed by lipase. Under… read more here.
Keywords: alkyl benzohydrazides; chemistry; synthesis alkyl; lipase ... See more keywords
BciC‐Catalyzed C132‐Demethoxycarbonylation of Metal Pheophorbide a Alkyl Esters
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DOI: 10.1002/cbic.201900745
Abstract: Bacteriochlorophyll c molecules self‐aggregate to form large oligomers in the core part of chlorosomes, which are the main light‐harvesting antenna systems of green photosynthetic bacteria. In the biosynthetic pathway of bacteriochlorophyll c, a BciC enzyme catalyzes the… read more here.
Keywords: alkyl; pheophorbide alkyl; bcic enzyme; bcic ... See more keywords
Benzoimidazole‐Pyridylamido Zirconium and Hafnium Alkyl Complexes as Homogeneous Catalysts for Tandem Carbon Dioxide Hydrosilylation to Methane
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DOI: 10.1002/cctc.201800077
Abstract: Neutral ZrIV and HfIV alkyl/amido complexes stabilized by a tridentate N ligand that contains a “rolling” heterodentate benzoimidazole fragment have been prepared and characterized. The ultimate nature of the ligand denticity, the electronic properties of… read more here.
Keywords: alkyl; pyridylamido zirconium; hydrosilylation; methane ... See more keywords
Separation and determination of alkyl sulfate surfactants in wastewater by capillary electrophoresis coupled with contactless conductivity detection after preconcentration by simultaneous adsorption using alumina beads
Sign Up to like & getrecommendations! Published in 2020 at "ELECTROPHORESIS"
DOI: 10.1002/elps.202000086
Abstract: The aim of the present study is to determine four anionic alkyl sulfate (AS) surfactants with different alkyl chains, namely, C8, C10, C12, and C14, in wastewater by CE with capacitively coupled contactless conductivity detection… read more here.
Keywords: alkyl; adsorption; simultaneous adsorption; surfactants wastewater ... See more keywords
Complete Genome Sequence of Sphingobium baderi DE-13, an Alkyl-Substituted Aniline-Mineralizing Bacterium
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DOI: 10.1007/s00284-017-1346-3
Abstract: Alkyl-substituted aniline is an important aniline derivative that may be associated with serious environmental risks. Previously, Sphingobium baderi DE-13, a bacterium that can mineralize alkyl substituted anilines such as 2,6-dimethylaniline, 2,6-diethylaniline, 2-methyl-6-ethylaniline, 2-methylaniline, and 2-ethylaniline,… read more here.
Keywords: alkyl; genome sequence; alkyl substituted; substituted aniline ... See more keywords
Synthesis and structure of alkyl 2-arylsulfanyl-3-nitroacrylates
Sign Up to like & getrecommendations! Published in 2018 at "Russian Chemical Bulletin"
DOI: 10.1007/s11172-018-2142-3
Abstract: Alkyl 2-arylsulfanyl-3-nitroacrylates were synthesized by the conjugate Michael addition of thiophenols to alkyl 3-bromo-3-nitroacrylates followed by elimination of HBr on treatment with Et3N. When treated with 4-chlorothiophenol in the presence of Et3N, alkyl 2-[(4-chlorophenyl) sulfanyl]-3-nitroacrylates… read more here.
Keywords: alkyl; alkyl arylsulfanyl; synthesis structure; structure alkyl ... See more keywords
One-step photolytic synthesis of hydrophobic porous polymer materials by the copolymerization of the dimethacrylate—alkyl methacrylate system in the presence of methanol
Sign Up to like & getrecommendations! Published in 2019 at "Russian Chemical Bulletin"
DOI: 10.1007/s11172-019-2620-2
Abstract: Hydrophobic porous polymer materials were synthesized by one-step visible light polymerization from compositions consisting of phthalate-containing oligoester di(meth)acrylate MDP-2, methanol, and alkyl methacrylate (butyl methacrylate, ethylhexyl methacrylate, iso-decyl methacrylate, lauryl methacrylate, and stearyl methacrylate) compositions.… read more here.
Keywords: alkyl; hydrophobic porous; one step; porous polymer ... See more keywords
Interpretation of Both Electron Pushing and Electron Withdrawing Inductive Effect of Alkyl Groups in Terms of Mulliken-Jaffe’s Charge Coefficient Parameters (b)
Sign Up to like & getrecommendations! Published in 2019 at "Resonance"
DOI: 10.1007/s12045-019-0798-0
Abstract: Alkyl groups can delocalize both the negative and positive charges through ion (charge)-induced dipole interaction with the polarizable alkyl groups. This charge induced polarization of the alkyl group to delocalize the charge is the origin… read more here.
Keywords: alkyl; inductive effect; effect alkyl; charge ... See more keywords
Synthesis and evaluation of sulfosuccinate-based surfactants as counterions for hydrophobic ion pairing.
Sign Up to like & getrecommendations! Published in 2022 at "Acta biomaterialia"
DOI: 10.1016/j.actbio.2022.03.013
Abstract: Hydrophobic ion pairing is a promising strategy to raise the lipophilic character of therapeutic peptides and proteins. In past studies, docusate, an all-purpose surfactant with a dialkyl sulfosuccinate structure, showed highest potential as hydrophobic counterion.… read more here.
Keywords: ion pairing; hydrophobic ion; sulfosuccinate; dioleyl sulfosuccinate ... See more keywords
Mixing behaviour of bilayer-forming phosphatidylcholines with single-chain alkyl-branched bolalipids: effect of lateral chain length.
Sign Up to like & getrecommendations! Published in 2019 at "Biophysical chemistry"
DOI: 10.1016/j.bpc.2018.10.003
Abstract: Liposomes are a promising class of drug delivery vehicles. However, no liposomal formulation has been approved for an oral application so far, due to stability issues of the liposomes in the gastrointestinal tract. Herein, we… read more here.
Keywords: alkyl; chain; chain alkyl; bilayer ... See more keywords
Thermal properties of silica-based hybrids with different alkyl chains
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DOI: 10.1016/j.ceramint.2016.09.161
Abstract: Abstract The thermal properties of silica-based hybrid coatings containing alkyl chains of varying lengths were examined. The hybrid coatings with alkyl chains showed a higher thermal diffusivity than silica-only coatings. The thermal diffusivity increased with… read more here.
Keywords: alkyl; properties silica; based hybrids; silica based ... See more keywords