Alkyl-Alkyl Interactions in the Periphery of Supramolecular Entities: From the Evaluation of Weak Forces to Applications.
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DOI: 10.1002/cplu.202000077
Abstract: Supramolecular chemistry is based on weak intermolecular forces which nevertheless are of importance for chemical processes. In this report the relevance of alkyl-alkyl interactions in supramolecular assemblies is discussed. We show how hierarchically formed helicates… read more here.
Keywords: entities evaluation; alkyl interactions; interactions periphery; supramolecular entities ... See more keywords
Catalytic Enantioconvergent Couplings of Secondary and Tertiary Electrophiles with Olefins
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DOI: 10.1038/s41586-018-0669-y
Abstract: Carbon–carbon bonds, including those between sp3-hybridized carbon atoms (alkyl–alkyl bonds), typically comprise much of the framework of organic molecules. In the case of sp3-hybridized carbon, the carbon can be stereogenic and the particular stereochemistry can… read more here.
Keywords: alkyl; carbon; tertiary electrophiles; electrophiles olefins ... See more keywords
Nickel-catalyzed migratory alkyl–alkyl cross-coupling reaction†
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DOI: 10.1039/d0sc03217d
Abstract: The selective cross-coupling of activated electrophiles with unactivated ones has been regarded as a challenging task in cross-electrophile couplings. Herein we describe a migratory cross-coupling strategy, which can overcome this obstacle to access the desired… read more here.
Keywords: alkyl cross; cross; reaction; cross coupling ... See more keywords
DFT insight into asymmetric alkyl–alkyl bond formation via nickel-catalysed enantioconvergent reductive coupling of racemic electrophiles with olefins
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DOI: 10.1039/d1sc05605k
Abstract: A DFT study has been conducted to understand the asymmetric alkyl–alkyl bond formation through nickel-catalysed reductive coupling of racemic alkyl bromide with olefin in the presence of hydrosilane and K3PO4. The key findings of the… read more here.
Keywords: asymmetric alkyl; alkyl; alkyl bond; bond formation ... See more keywords