Recent progress in C(aryl)–C(alkyl) bond cleavage of alkylarenes
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DOI: 10.1039/c9qo01438a
Abstract: Cleavage of the C(aryl)–C(alkyl) σ-bond is important both in academy and industry as it holds the potential to provide straightforward access to a variety of targets from readily available chemical feedstocks such like alkylarenes. However,… read more here.
Keywords: recent progress; cleavage; aryl alkyl; alkyl bond ... See more keywords
DFT insight into asymmetric alkyl–alkyl bond formation via nickel-catalysed enantioconvergent reductive coupling of racemic electrophiles with olefins
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DOI: 10.1039/d1sc05605k
Abstract: A DFT study has been conducted to understand the asymmetric alkyl–alkyl bond formation through nickel-catalysed reductive coupling of racemic alkyl bromide with olefin in the presence of hydrosilane and K3PO4. The key findings of the… read more here.
Keywords: asymmetric alkyl; alkyl; alkyl bond; bond formation ... See more keywords
Exploring Electrolyte Effects on Metal-Alkyl Bond Stability: Impact and Implications for Electrosynthesis
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DOI: 10.1039/d3fd00054k
Abstract: Transition metal catalysis hinges on the formation of metal-carbon bonds during catalytic cycles. The stability and reactivity of these bonds are what determine product chemo-, regio-, and enantioselectivity. The advent... read more here.
Keywords: effects metal; metal alkyl; alkyl bond; exploring electrolyte ... See more keywords