Visible-Light-Mediated Alkenylation of Alkyl Boronic Acids without an External Lewis Base as an Activator.
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DOI: 10.1021/acs.orglett.1c00399
Abstract: Herein we report a protocol for the direct visible-light-mediated alkenylation of alkyl boronic acids at room temperature without an external Lewis base as an activator, and we propose a mechanism involving benzenesulfinate activation of the… read more here.
Keywords: mediated alkenylation; boronic acids; light mediated; visible light ... See more keywords
Cooperative Photoredox and N-Heterocyclic Carbene Catalysis Suzuki-Miyaura-Type Reaction: Radical Coupling of Aroyl Fluorides and Alkyl Boronic Acids.
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DOI: 10.1021/acs.orglett.4c00334
Abstract: An intermolecular Suzuki-Miyaura-type reaction of benzoyl fluorides with alkyl boronic acids to synthetic ketone was revealed by cooperative N-heterocyclic carbene (NHC) and photoredox catalysis. Various alkyl boric acids can be converted into alkyl radicals without… read more here.
Keywords: reaction; alkyl boronic; fluorides alkyl; suzuki miyaura ... See more keywords