Rh(I)-Catalyzed C6-Selective Decarbonylative Alkylation of 2-Pyridones with Alkyl Carboxylic Acids and Anhydrides.
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DOI: 10.1021/acs.orglett.0c01277
Abstract: A Rh-catalyzed chelation-assisted C6-selective C-H activation/alkylation of 2-pyridones with readily available alkyl carboxylic acids or anhydrides is introduced. The reaction proceeds via substrate decarbonylation. This approach merges C-H functionalization with readily available anhydrides, allowing for… read more here.
Keywords: alkyl carboxylic; catalyzed selective; carboxylic acids; alkylation pyridones ... See more keywords
Oxidative decarboxylative radical trifluoromethylthiolation of alkyl carboxylic acids with silver(I) trifluoromethanethiolate and selectfluor
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DOI: 10.1039/c6ra26133g
Abstract: A straightforward silver-mediated oxidative decarboxylative radical trifluoromethylthiolation reaction of aliphatic carboxylic acid is described. This reaction operates under mild conditions and allows the synthesis of various valuable alkyltrifluoromethylthioethers from abundant alkyl carboxylic acids and convenient… read more here.
Keywords: alkyl carboxylic; carboxylic acids; oxidative decarboxylative; radical trifluoromethylthiolation ... See more keywords