Luminescent Cyclometalated Gold(III) Alkyl Complexes: Photophysical and Photochemical Properties.
Sign Up to like & getrecommendations! Published in 2017 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.7b00180
Abstract: A series of luminescent cyclometalated gold(III) complexes having alkyls as auxiliary ligands has been prepared. The alkyl ligand was found to effectively increase the emission quantum yields and lifetimes of luminescent cyclometalated gold(III) complexes by… read more here.
Keywords: iii alkyl; alkyl complexes; gold iii; luminescent cyclometalated ... See more keywords
Aluminium alkyl complexes supported by imino-phosphanamide ligand as precursors for catalytic guanylation reactions of carbodiimides
Sign Up to like & getrecommendations! Published in 2022 at "RSC Advances"
DOI: 10.1039/d2ra00242f
Abstract: Herein, we report the synthesis, characterisation, and application of three aluminium alkyl complexes, [κ2-{NHIRP(Ph)NDipp}AlMe2] (R = Dipp (2a), Mes (2b); tBu (2c), Dipp = 2,6-diisopropylphenyl, Mes = mesityl, and tBu = tert-butyl), supported by unsymmetrical… read more here.
Keywords: alkyl complexes; guanylation; imino phosphanamide; aluminium alkyl ... See more keywords
Aluminum Alkyl Complexes Bearing Salicylaldiminato Ligands : Versatile Initiators in the Ring-Opening Polymerization of Cyclic Esters
Sign Up to like & getrecommendations! Published in 2017 at "Catalysts"
DOI: 10.3390/catal7020064
Abstract: Linear aliphatic polyesters are degradable thermoplastic polymers, which can be obtained by ring-opening polymerization (ROP) of cyclic esters through a coordination-insertion mechanism. Aluminum b ... read more here.
Keywords: alkyl complexes; ring opening; opening polymerization; aluminum alkyl ... See more keywords