Copper-Catalyzed Radical 1,4-Difunctionalization of 1,3-Enynes with Alkyl Diacyl Peroxides and N-Fluorobenzenesulfonimide.
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DOI: 10.1021/jacs.8b11499
Abstract: Many reactions involving allenyl ion species have been studied, but reactions involving allenyl radicals are less well understood, perhaps because of the inconvenience associated with the generation of short-lived allenyl radicals. We describe here a… read more here.
Keywords: alkyl diacyl; allenyl radicals; diacyl peroxides; peroxides fluorobenzenesulfonimide ... See more keywords
Copper(I)-catalyzed tandem reaction: synthesis of 1,4-disubstituted 1,2,3-triazoles from alkyl diacyl peroxides, azidotrimethylsilane, and alkynes
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DOI: 10.3762/bjoc.14.270
Abstract: A copper-catalyzed azide–alkyne cycloaddition (CuAAC) reaction for the synthesis of 1,4-disubstituted 1,2,3-triazoles from alkyl diacyl peroxides, azidotrimethylsilane, and terminal alkynes is reported. The alkyl carboxylic acids is for the first time being used as the… read more here.
Keywords: reaction synthesis; alkyl diacyl; diacyl peroxides; synthesis disubstituted ... See more keywords