Catalytic Alkyl Hydroperoxide and Acyl Hydroperoxide Disproportionation by a Nonheme Iron Complex
Sign Up to like & getrecommendations! Published in 2018 at "ACS Catalysis"
DOI: 10.1021/acscatal.8b02882
Abstract: Alkyl hydroperoxides are commonly used as terminal oxidants because they are generally acknowledged to be stable toward disproportionation compared with H2O2. We show that alkylperoxide disproportionation is effectively catalyzed by the [Fe(tpena)]2+ (tpena = N,N,N′-tris(2-pyridylmethyl)ethylendiamine-N′-acetate).… read more here.
Keywords: alkyl; catalytic alkyl; alkyl hydroperoxide; iron ... See more keywords
Alkane Solvent-Derived Acylation Reaction Driven by Electric Fields.
Sign Up to like & getrecommendations! Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.3c02064
Abstract: Electric field acceleration of alkyl hydroperoxide activation to acylate amines in the scanning tunneling microscope-based break-junction is reported. Alkyl hydroperoxide mixtures, generated from hydrocarbon autoxidation in air, were found to be competent reagents for the… read more here.
Keywords: alkane solvent; reaction driven; solvent derived; acylation reaction ... See more keywords