Articles with "alkyl mesylates" as a keyword



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Preparation of Enantioenriched Alkylcarbastannatranes via Nucleophilic Inversion of Alkyl Mesylates for Use in Stereospecific Cross-Coupling Reactions.

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Published in 2019 at "Organometallics"

DOI: 10.1021/acs.organomet.9b00467

Abstract: We report the preparation of enantioenriched secondary alkylcarbastannatranes via a stereoinvertive SN2 reaction of enantioenriched alkyl mesylates and carbastannatranyl anion equivalents. Using this process, enantioenriched secondary alcohols may be converted into highly enantioenriched alkylcarbastannatranes, which… read more here.

Keywords: alkyl mesylates; enantioenriched alkylcarbastannatranes; stereospecific cross; alkylcarbastannatranes via ... See more keywords