Iron-Catalyzed Dehydrative Alkylation of Propargyl Alcohol with Alkyl Peroxides To Form Substituted 1,3-Enynes.
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DOI: 10.1021/acs.orglett.8b01043
Abstract: This paper reports a new method for the generation of substituted 1,3-enynes, whose synthesis by other methods could be a challenge. The dehydrative decarboxylative cascade coupling reaction of propargyl alcohol with alkyl peroxides is enabled… read more here.
Keywords: alkyl; alkyl peroxides; alcohol alkyl; substituted enynes ... See more keywords
A Metal-Free Approach for Brønsted Acid Promoted C–H Alkylation of Heteroarenes with Alkyl Peroxides
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DOI: 10.1055/s-0037-1609965
Abstract: A metal-free protocol for Minisci C–H alkylation of heteroarenes using alkyl peroxides as the alkylating reagents and internal oxidants simultaneously under promotion of Bronsted acid has been demonstrated. A series of alkyl substituted heteroarenes were… read more here.
Keywords: nsted acid; alkyl peroxides; acid promoted; approach nsted ... See more keywords