Copper-Catalyzed Cross-Coupling of Alkyl and Phosphorus Radicals for C(sp3)-P Bond Formation.
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DOI: 10.1021/acs.orglett.2c02454
Abstract: A CuI-catalyzed cross-coupling of alkyl- and phosphorus-centered radicals for C(sp3)-P bond formation is introduced. Diacyl peroxides, generated in situ from aliphatic acids and H2O2, serve as a source for alkyl radicals and also an initiator… read more here.
Keywords: coupling alkyl; alkyl phosphorus; cross coupling; phosphorus ... See more keywords