Origin of Regio‐ and Stereoselectivity in the NHC‐catalyzed Reaction of Alkyl Pyridinium with Aliphatic Enal
Sign Up to like & getrecommendations! Published in 2019 at "ChemCatChem"
DOI: 10.1002/cctc.201901965
Abstract: The mechanisms of N‐heterocyclic carbene (NHC)‐catalyzed dearomatization reaction of alkyl pyridinium have been intensively studied using the density functional theory (DFT) method. The chemoselectivity and stereoselectivity were both analyzed based on the established mechanisms. The… read more here.
Keywords: nhc catalyzed; alkyl pyridinium; reaction alkyl; stereoselectivity ... See more keywords
Measurements of the solubility parameter and enthalpies of vaporization in N-alkyl-pyridinium bis((trifluoromethyl)sulfonyl)imide ([CnPY][NTF2], n = 4,6,8) ionic liquid
Sign Up to like & getrecommendations! Published in 2019 at "Fluid Phase Equilibria"
DOI: 10.1016/j.fluid.2018.12.014
Abstract: Abstract Some thermodynamic and physicochemical properties of N-alkyl-pyridinium bis((trifluoromethyl)sulfonyl)imide ([CnPY][NTF2], n = 4, 6, 8) ionic liquids (ILs) were investigated through inverse gas chromatography at temperatures from 333.15 K to 373.15 K. A total of 23 solvents were used… read more here.
Keywords: sulfonyl imide; alkyl pyridinium; trifluoromethyl sulfonyl; pyridinium bis ... See more keywords
Supramolecular hydrogels prepared from fluorescent alkyl pyridinium acrylamide monomers and CB[8]
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DOI: 10.1039/d0py01374a
Abstract: We introduce a new facile synthetic methodology for the preparation of alkyl pyridinium-containing acrylamide monomers. Inclusion complexes of these new monomers with CB[8] facilitate supramolecular crosslinking in a series of hydrogels formed through in situ… read more here.
Keywords: supramolecular hydrogels; alkyl pyridinium; prepared fluorescent; acrylamide monomers ... See more keywords
Novel Keto-Alkyl-Pyridinium Antifungal Molecules Active in Models of In Vivo Candida albicans Vascular Catheter Infection and Ex Vivo Candida auris Skin Colonization
Sign Up to like & getrecommendations! Published in 2023 at "Antimicrobial Agents and Chemotherapy"
DOI: 10.1128/aac.00081-23
Abstract: New antifungal therapies are needed for both systemic, invasive infections in addition to superficial infections of mucosal and skin surfaces as well as biofilms associated with medical devices. The resistance of biofilm and biofilm-like growth… read more here.
Keywords: keto alkyl; vivo candida; alkyl pyridinium;