Synthesis of N-aryl and N-alkyl substituted imidazolium silver complexes. Cytotoxic screening using human cell lines modelling acute myeloid leukemia.
Sign Up to like & getrecommendations! Published in 2020 at "ChemMedChem"
DOI: 10.1002/cmdc.202000138
Abstract: A series of N- aryl and N- alkyl substituted imidazoles were synthesized and complexed with Ag + to obtain silver-NHC complexes of the form [Ag(NHC)2 ]X. These silver-NHC complexes were tested in-vitro versus the human… read more here.
Keywords: alkyl substituted; cell lines; myeloid leukemia; aryl alkyl ... See more keywords
Complete Genome Sequence of Sphingobium baderi DE-13, an Alkyl-Substituted Aniline-Mineralizing Bacterium
Sign Up to like & getrecommendations! Published in 2017 at "Current Microbiology"
DOI: 10.1007/s00284-017-1346-3
Abstract: Alkyl-substituted aniline is an important aniline derivative that may be associated with serious environmental risks. Previously, Sphingobium baderi DE-13, a bacterium that can mineralize alkyl substituted anilines such as 2,6-dimethylaniline, 2,6-diethylaniline, 2-methyl-6-ethylaniline, 2-methylaniline, and 2-ethylaniline,… read more here.
Keywords: alkyl; genome sequence; alkyl substituted; substituted aniline ... See more keywords
Synthesis and Analgesic Activity of 4,7-Dimethyl-3,4,4a,5,8,8a-Hexahydro-2-Chromen-4,8-Diols Containing Alkyl-Substituted Aromatic Moieties
Sign Up to like & getrecommendations! Published in 2017 at "Chemistry of Natural Compounds"
DOI: 10.1007/s10600-017-2202-1
Abstract: A series of new heterocyclic compounds with the hexahydro-2H-chromene skeleton were prepared by reacting the monoterpenoid para-mentha-1,8-diene-5,6-diol with 4-alkyl-substituted aromatic aldehydes. Adding small alkyl substituents (methyl and ethyl) to the aldehyde aromatic ring increased the… read more here.
Keywords: activity dimethyl; alkyl substituted; substituted aromatic; synthesis analgesic ... See more keywords
Single crystal preparation and x-ray structure analysis of non-peripherally alkyl-substituted phthalocyanine blends
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Crystal Growth"
DOI: 10.1016/j.jcrysgro.2016.11.095
Abstract: Abstract Single crystals of non-peripherally alkyl-substituted macrocycle molecules, such as octahexylphthalocyanine (C6PcH 2 ), octapentylphthalocyanine (C5PcH 2 ), octahexyltetrabenzotriazaporphyrin (C6TBTAPH 2 ), and their blends were prepared. The crystal structures of C6PcH 2 and C5PcH… read more here.
Keywords: non peripherally; alkyl substituted; peripherally alkyl; single crystal ... See more keywords
Preferential degradation of long-chain alkyl substituted hydrocarbons in heavy oil under methanogenic conditions
Sign Up to like & getrecommendations! Published in 2019 at "Organic Geochemistry"
DOI: 10.1016/j.orggeochem.2019.103927
Abstract: Abstract Methanogenic crude oil degradation is a significant process in subsurface environments and degradation of crude oil n-alkanes has been well documented. However, little is known about the biodegradability of the resulting heavy oil. In… read more here.
Keywords: degradation; alkyl substituted; long chain; heavy oil ... See more keywords
[Co/Fe(α-Alkyl-tpdt)2]x-: Alkyl-Substituted Cobalt and Iron Bis-dithiolenethiophenic Complexes.
Sign Up to like & getrecommendations! Published in 2020 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.0c01154
Abstract: Tetraphenylphosphonium salts of Co and Fe complexes with alkyl-substituted, tert-butyl (tb), and isopropyl (dp) 2,3-thiophenedithiolate (α-tpdt) ligands, namely, TPP[Co(α-tb-tpdt)2] (3), TPP2[Fe(α-tb-tpdt)2]2 (4a-b), TPP[Co(α-dp-tpdt)2] (5), and TPP[Fe(α-dp-tpdt)2] (6) were prepared and characterized by cyclic voltammetry, single… read more here.
Keywords: alkyl tpdt; alkyl substituted; tpp tpdt; complexes alkyl ... See more keywords
Regio- and Enantioselective Iridium-Catalyzed Amination of Alkyl-Substituted Allylic Acetates with Secondary Amines.
Sign Up to like & getrecommendations! Published in 2021 at "Organic letters"
DOI: 10.1021/acs.orglett.1c04135
Abstract: Robust air-stable cyclometalated π-allyliridium C,O-benzoates modified by (S)-tol-BINAP catalyze the reaction of secondary aliphatic amines with racemic alkyl-substituted allylic acetates to furnish products of allylic amination with high levels of enantioselectivity. Complete branched regioselectivities were… read more here.
Keywords: amination; regio enantioselective; substituted allylic; alkyl substituted ... See more keywords
A General Procedure for the Construction of 2-Alkyl-Substituted Vinyl Sulfonyl Fluoride.
Sign Up to like & getrecommendations! Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c03936
Abstract: A series of compact and multifunctional 2-alkyl-substituted vinyl sulfonyl fluorides were efficiently prepared from the corresponding alkyl iodides and 2-chloroprop-2-ene-1-sulfonyl fluoride (CESF). This Giese-type radical approach provided new and general access to alkenyl sulfonyl fluorides,… read more here.
Keywords: vinyl sulfonyl; substituted vinyl; sulfonyl fluoride; sulfonyl ... See more keywords
Alkyl-Substituted N,S-Embedded Heterocycloarenes with a Planar Aromatic Configuration for Hosting Fullerenes and Organic Field-Effect Transistors.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c08276
Abstract: Cycloarenes and heterocycloarenes display unique physical structures and hold great potential as organic semiconductors. However, the synthesis of (hetero)cycloarenes remains a big challenge, and there are limited reports on their applications. Herein, a series of… read more here.
Keywords: field effect; effect transistors; configuration; alkyl substituted ... See more keywords
An alkyl-substituted aluminium anion with strong basicity and nucleophilicity
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DOI: 10.1038/s41557-019-0365-z
Abstract: Aluminium anions with an unoccupied orbital are generally considered as highly difficult synthetic targets, as aluminium is the most electropositive element in the p block. Stabilizing effects from two nitrogen substituents and/or the coordination of… read more here.
Keywords: anion; alkyl substituted; aluminium; strong basicity ... See more keywords
Nickel-catalysed direct α-olefination of alkyl substituted N-heteroarenes with alcohols.
Sign Up to like & getrecommendations! Published in 2019 at "Chemical communications"
DOI: 10.1039/c9cc03591e
Abstract: Catalytic α-olefination of alkylheteroarenes with primary alcohols via dehydrogenative coupling is presented. A simple nickel catalyst system stabilised by readily available nitrogen ligands enables a series of interesting E-configured vinylarenes (confirmed by X-ray crystal-structure analysis)… read more here.
Keywords: alkyl substituted; nickel catalysed; olefination; catalysed direct ... See more keywords