Controllable, Sequential, and Stereoselective C-H Allylic Alkylation of Alkenes.
Sign Up to like & getrecommendations! Published in 2019 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.9b08801
Abstract: The direct conversion of C-H bonds into new C-C bonds represents a powerful approach to generate complex molecules from simple starting materials. However, a general and controllable method for the sequential conversion of a methyl… read more here.
Keywords: sequential stereoselective; controllable sequential; alkylation alkenes; allylic alkylation ... See more keywords
(Fluoro)alkylation of alkenes promoted by photolysis of alkylzirconocenes
Sign Up to like & getrecommendations! Published in 2022 at "Chemical Science"
DOI: 10.1039/d1sc07061d
Abstract: Difluoroalkylated compounds have important applications in pharmaceutical, agrochemical, and materials science. However, efficient methods to construct the alkylCF2–alkyl bond are very limited, and the site-selective introduction of a difluoromethylene (CF2) group into an aliphatic chain… read more here.
Keywords: alkenes promoted; fluoro alkylation; alkylation alkenes; photolysis alkylzirconocenes ... See more keywords